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Publications

2013

  • Microsecond ramp compression of a metallic liner driven by a 5 MA current on the SPHINX machine using a dynamic load current multiplier pulse shaping
    • d'Almeida Thierry
    • Lassalle Francis
    • Morell Alain
    • Grunenwald Julien
    • Zucchini Frédéric
    • Loyen Arnaud
    • Maysonnave Thomas
    • Chuvatin Alexandre S.
    Physics of Plasmas, American Institute of Physics, 2013, 20 (09), pp.092512. SPHINX is a 6 MA, 1-μs Linear Transformer Driver (LTD) operated by the CEA Gramat (France) and primarily used for imploding Z-pinch loads for radiation effects studies. Among the options that are currently being evaluated to improve the generator performances are an upgrade to a 20 MA, 1-μs LTD machine and various power amplification schemes, including a compact Dynamic Load Current Multiplier (DLCM). A method for performing magnetic ramp compression experiments, without modifying the generator operation scheme, was developed using the DLCM to shape the initial current pulse in order to obtain the desired load current profile. In this paper, we discuss the overall configuration that was selected for these experiments, including the choice of a coaxial cylindrical geometry for the load and its return current electrode. We present both 3-D Magneto-hydrodynamic and 1D Lagrangian hydrodynamic simulations which helped guide the design of the experimental configuration. Initial results obtained over a set of experiments on an aluminium cylindrical liner, ramp-compressed to a peak pressure of 23 GPa, are presented and analyzed. Details of the electrical and laser Doppler interferometer setups used to monitor and diagnose the ramp compression experiments are provided. In particular, the configuration used to field both homodyne and heterodyne velocimetry diagnostics in the reduced access available within the liner's interior is described. Current profiles measured at various critical locations across the system, particularly the load current, enabled a comprehensive tracking of the current circulation and demonstrate adequate pulse shaping by the DLCM. The liner inner free surface velocity measurements obtained from the heterodyne velocimeter agree with the hydrocode results obtained using the measured load current as the input. An extensive hydrodynamic analysis is carried out to examine information such as pressure and particle velocity history profiles or magnetic diffusion across the liner. The potential of the technique in terms of applications and achievable ramp pressure levels lies in the prospects for improving the DLCM efficiency through the use of a closing switch (currently under development), reducing the load dimensions and optimizing the diagnostics. (10.1063/1.4823720)
    DOI : 10.1063/1.4823720
  • Electron nongyrotropy in the context of collisionless magnetic reconnection
    • Aunai Nicolas
    • Hesse Michael
    • Kuznetsova M. M.
    Physics of Plasmas, American Institute of Physics, 2013, 20, pp.2903. Collisionless magnetized plasmas have the tendency to isotropize their velocity distribution function around the local magnetic field direction, i.e., to be gyrotropic, unless some spatial and/or temporal fluctuations develop at the particle gyroscales. Electron gyroscale inhomogeneities are well known to develop during the magnetic reconnection process. Nongyrotropic electron velocity distribution functions have been observed to play a key role in the dissipative process breaking the field line connectivity. In this paper, we present a new method to quantify the deviation of a particle population from gyrotropy. The method accounts for the full 3D shape of the distribution and its analytical formulation allows fast numerical computation. Regions associated with a significant degree of nongyrotropy are shown, as well as the kinetic origin of the nongyrotropy and the fluid signature it is associated with. Using the result of 2.5D Particle-In-Cell simulations of magnetic reconnection in symmetric and asymmetric configurations, it is found that neither the reconnection site nor the topological boundaries are generally associated with a maximized degree of nongyrotropy. Nongyrotropic regions do not correspond to a specific fluid behavior as equivalent nongyrotropy is found to extend over the electron dissipation region as well as in non-dissipative diamagnetic drift layers. The localization of highly nongyrotropic regions in numerical models and their correlation with other observable quantities can, however, improve the characterization of spatial structures explored by spacecraft missions. (10.1063/1.4820953)
    DOI : 10.1063/1.4820953
  • Antisunward structure of thin current sheets in the Earth's magnetotail : Implications of quasi-adiabatic theory
    • Malova H. V.
    • Popov V. Y.
    • Delcourt Dominique C.
    • Petrukovich A. A.
    • Zelenyi L. M.
    Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2013, 118. We developed a self-consistent kinetic model of thin current sheets (TCS), taking into account the inhomogeneity of TCS parameters in the antisunward direction. We show that the charged particle dynamics depending on the magnetic field distribution in the downtail direction completely determines the magnetotail equilibrium structure. We demonstrate that transient ions as well as electrons are the main current carriers in this system, but the first ones support mostly the background (1-D) structure of the current sheet. The influence of electrons and quasi-trapped ions is found to vary depending upon downtail distance along the sheet. Assuming the conservation of the so-called quasi-adiabatic invariant, we show that quasi-trapped particles are distributed along the current sheet in such a way that they concentrate in the region with large values of normal magnetic field component. As a result quasi-trapped ions can dominate near the earthward edge of TCS. In contrast, the electron current becomes stronger in the TCS tailward region where the normal magnetic field component becomes weaker, and field line curvature drifts are enhanced. Our quasi-adiabatic model predicts that thin current sheets in the Earth's magnetotail should have weakly 2-D configuration which, similar to its 1-D analog considered earlier, conserves the multiscale matreshka structure with multiple embedded layers. (10.1002/jgra.50390)
    DOI : 10.1002/jgra.50390
  • Inner radiation belt particle acceleration and energy structuring by drift resonance with ULF waves during geomagnetic storms
    • Delcourt Dominique C.
    • Benoist C.
    • Penou E.
    • Chen Y.
    • Russell C. T.
    • Sauvaud J.-A.
    • Walt M.
    Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2013, 118 (4), pp.1723-1736. Geomagnetic storms are frequently associated with the formation of multiple bands of energetic electrons inside the inner radiation belt at L = 1.1-1.9 and with prominent energy structures of protons inside the slot region at L = 2.2-3.5. These structures typically from 100 keV up to the MeV range result from coherent interactions of energetic particles with quasi-monochromatic ultra-low frequency (ULF) waves. These waves are induced by magnetospheric changes due to the arrival of dense solar material and related nightside injections of particles from the outer magnetosphere that destabilize field lines in the inner magnetosphere down to L = 1.1. Using low-altitude data from the polar orbiting Demeter spacecraft, we perform case and statistical studies of these structures. We show that with such a spacecraft, these structures are best seen near the South Atlantic Anomaly because of lowering of the belt particle mirror point. As evidenced from ground measurements, energy bands are associated with quasi-sinusoidal ULF Pc5 and Pc4 waves with periods in the 1000 s range for L = 1.1-1.9 and in the 60 s range for L = 2.2-3.5. Numerical simulations of the coherent drift resonance of energetic particles with ultra-low frequency waves show how the particles are accelerated and how the observed structures build up. (10.1002/jgra.50125)
    DOI : 10.1002/jgra.50125
  • Energetic electron acceleration by unsteady magnetic reconnection
    • Fu H.S.
    • Khotyaintsev Y. V.
    • Vaivads A.
    • Retinò Alessandro
    • André M.
    Nature Physics, Nature Publishing Group [2005-....], 2013, 9, pp.426-430. The mechanism that produces energetic electrons during magnetic reconnection is poorly understood. This is a fundamental process responsible for stellar flares, substorms, and disruptions in fusion experiments. Observations in the solar chromosphere and the Earth's magnetosphere indicate significant electron acceleration during reconnection, whereas in the solar wind, energetic electrons are absent. Here we show that energetic electron acceleration is caused by unsteady reconnection. In the Earth's magnetosphere and the solar chromosphere, reconnection is unsteady, so energetic electrons are produced; in the solar wind, reconnection is steady, so energetic electrons are absent. The acceleration mechanism is quasi-adiabatic: betatron and Fermi acceleration in outflow jets are two processes contributing to electron energization during unsteady reconnection. The localized betatron acceleration in the outflow is responsible for at least half of the energy gain for the peak observed fluxes. (10.1038/nphys2664)
    DOI : 10.1038/nphys2664
  • Isopropanol saturated TiO<SUB>2</SUB> surface regeneration by non-thermal plasma : Influence of air relative humidity
    • Sivachandiran Loganathan
    • Thévenet Frédéric
    • Gravejat Paul
    • Rousseau Antoine
    Chemical Engineering Journal, Elsevier, 2013, 214, pp.17-26. Environmental regulation on air quality requires the development of energetic efficient volatile organic compounds (VOCs) abatement techniques. Adsorption, photocatalysis, non-thermal plasma and their combinations have been widely studied for VOC treatment. Even if the plasma material (sorbent or catalyst) association appears as one of the most efficient configuration for VOC removal, it mainly consists in operating continuously the discharge on the material surface as long as the effluent flows across the reactor. This work aims at investigating another approach of plasma material association for VOC removal: in a first step, the material is used as a sorbent until the complete coverage of adsorption sites; in a second step, once VOC saturation is achieved, the discharge is ignited on the material surface. During both steps, the influence of air relative humidity (RH) is investigated in order to evaluate its impact on the process. The objectives of our approach are: (i) the reduction of energy consumption; (ii) the increase of sorbent life-times by efficient regeneration; (iii) the investigation of plasma interaction with VOC saturated materials; (iv) the investigation of air RH influence on such VOC treatment process. A packed bed reactor coated with TiO2 has been designed. IPA is used as a model VOC. First, injected power in the packed-bed reactor is characterized as a function of air RH. Complete coverage of TiO2 surface over 35% RH is suggested as a significant parameter. Then, adsorption of IPA on TiO2 was monitored until IPA breakthrough. The amount of IPA adsorbed per TiO2 surface unit is compared to values reported by other authors. The influence of air RH on reversibly and irreversibly adsorbed IPA fractions is investigated. Over 35% RH irreversible adsorption is favored, adsorption modes are discussed. Plasma regeneration of IPA saturated TiO2 surface leads simultaneously to IPA desorption and mineralization. Increasing air RH favors IPA mineralization and diminishes acetone production. Carbon balance obtained after 1 h plasma treatment reaches 91% in the presence of 50% RH. A thermal treatment is performed after each plasma treatment in order to evidence plasma insensitive adsorbed species and to restore TiO2 initial surface state. 97% of the carbon balance is collected under 50% RH after thermal treatment. During the thermal step, acetone and CO2 are mainly produced, their formation pathways are discussed. (10.1016/j.cej.2012.10.022)
    DOI : 10.1016/j.cej.2012.10.022
  • Influence of the dissipation mechanism on collisionless magnetic reconnection in symmetric and asymmetric current layers
    • Aunai Nicolas
    • Hesse Michael
    • Black Carrie
    • Evans Rebekah
    • Kuznetsova M. M.
    Physics of Plasmas, American Institute of Physics, 2013, 20, pp.2901. Numerical studies implementing different versions of the collisionless Ohm's law have shown a reconnection rate insensitive to the nature of the non-ideal mechanism occurring at the X line, as soon as the Hall effect is operating. Consequently, the dissipation mechanism occurring in the vicinity of the reconnection site in collisionless systems is usually thought not to have a dynamical role beyond the violation of the frozen-in condition. The interpretation of recent studies has, however, led to the opposite conclusion that the electron scale dissipative processes play an important dynamical role in preventing an elongation of the electron layer from throttling the reconnection rate. This work re-visits this topic with a new approach. Instead of focusing on the extensively studied symmetric configuration, we aim to investigate whether the macroscopic properties of collisionless reconnection are affected by the dissipation physics in asymmetric configurations, for which the effect of the Hall physics is substantially modified. Because it includes all the physical scales a priori important for collisionless reconnection (Hall and ion kinetic physics) and also because it allows one to change the nature of the non-ideal electron scale physics, we use a (two dimensional) hybrid model. The effects of numerical, resistive, and hyper-resistive dissipation are studied. In a first part, we perform simulations of symmetric reconnection with different non-ideal electron physics. We show that the model captures the already known properties of collisionless reconnection. In a second part, we focus on an asymmetric configuration where the magnetic field strength and the density are both asymmetric. Our results show that contrary to symmetric reconnection, the asymmetric model evolution strongly depends on the nature of the mechanism which breaks the field line connectivity. The dissipation occurring at the X line plays an important role in preventing the electron current layer from elongating and forming plasmoids. (10.1063/1.4795727)
    DOI : 10.1063/1.4795727
  • Remote sensing of a NTC radio source from a Cluster tilted spacecraft pair
    • Décréau Pierrette
    • Kougblénou S.
    • Lointier G.
    • Rauch Jean-Louis
    • Trotignon Jean-Gabriel
    • Vallières X.
    • Canu Patrick
    • Rochel Grimald S.
    • El-Lemdani Mazouz Farida
    • Darrouzet F.
    Annales Geophysicae, European Geosciences Union, 2013, 31 (11), pp.2097-2121. The Cluster mission operated a "tilt campaign" during the month of May 2008. Two of the four identical Cluster spacecraft were placed at a close distance (~50 km) from each other and the spin axis of one of the spacecraft pair was tilted by an angle of ~46°. This gave the opportunity, for the first time in space, to measure global characteristics of AC electric field, at the sensitivity available with long boom (88 m) antennas, simultaneously from the specific configuration of the tilted pair of satellites and from the available base of three satellites placed at a large characteristic separation (~1 RE). This paper describes how global characteristics of radio waves, in this case the configuration of the electric field polarization ellipse in 3-D-space, are identified from in situ measurements of spin modulation features by the tilted pair, validating a novel experimental concept. In the event selected for analysis, non-thermal continuum (NTC) waves in the 15-25 kHz frequency range are observed from the Cluster constellation placed above the polar cap. The observed intensity variations with spin angle are those of plane waves, with an electric field polarization close to circular, at an ellipticity ratio e = 0.87. We derive the source position in 3-D by two different methods. The first one uses ray path orientation (measured by the tilted pair) combined with spectral signature of magnetic field magnitude at source. The second one is obtained via triangulation from the three spacecraft baseline, using estimation of directivity angles under assumption of circular polarization. The two results are not compatible, placing sources widely apart. We present a general study of the level of systematic errors due to the assumption of circular polarization, linked to the second approach, and show how this approach can lead to poor triangulation and wrong source positioning. The estimation derived from the first method places the NTC source region in the dawn sector, at a large L value (L ~ 10) and a medium geomagnetic latitude (35° S). We discuss these untypical results within the frame of the geophysical conditions prevailing that day, i.e. a particularly quiet long time interval, followed by a short increase of magnetic activity. (10.5194/angeo-31-2097-2013)
    DOI : 10.5194/angeo-31-2097-2013
  • On the supply of heavy planetary material to the magnetotail of Mercury
    • Delcourt Dominique C.
    Annales Geophysicae, European Geosciences Union, 2013, 31 (10), pp.1673-1679. We examine the transport of low-energy heavy ions of planetary origin (O + , Na + , Ca +) in the magneto-sphere of Mercury. We show that, in contrast to Earth, these ions are abruptly energized after ejection into the magneto-sphere due to enhanced curvature-related parallel acceleration. Regardless of their mass-to-charge ratio, the parallel speed of these ions is rapidly raised up to ∼ 2 V E×B (denoting by V E×B the magnitude of the local E × B drift speed), in a like manner to Fermi-type acceleration by a moving magnetic mirror. This parallel energization is such that ions with very low initial energies (a few tenths of eVs) can overcome gravity and, regardless of species or convection rate, are transported over comparable distances into the night-side magnetosphere. The region of space where these ions reach the magnetotail is found to extend over altitudes similar to those where enhanced densities are noticeable in the MESSENGER data, viz., from ∼ 1000 km up to ∼ 6000 km in the pre-midnight sector. The observed density enhancements may thus follow from E × B related focusing of planetary material of dayside origin into the magnetotail. Due to the planetary magnetic field offset, an asymmetry is found between drift paths anchored in the Northern and Southern hemispheres, which puts forward a predominant role of heavy material originating in the Northern Hemisphere in populating the innermost region of Mercury's magnetotail. (10.5194/angeo-31-1673-2013)
    DOI : 10.5194/angeo-31-1673-2013
  • ECH effects on toroidal rotation: KSTAR experiments, intrinsic torque modelling and gyrokinetic stability analyses
    • Shi Y. J.
    • Ko W. H.
    • Kwon J.M.
    • Diamond P.H.
    • Lee S. G.
    • Ko S. H.
    • Wang L.
    • Yi Sukyoung
    • Ida K.
    • Terzolo L.
    • Yoon S. W.
    • Lee K. D.
    • Lee J. H.
    • Nam U. N.
    • Bae Y. S.
    • Oh Y. K.
    • Kwak J. G.
    • Bitter M.
    • Hill K.
    • Gürcan Özgür D.
    • Hahm T.S.
    Nuclear Fusion, IOP Publishing, 2013, 53 (11). Toroidal rotation profiles have been investigated in KSTAR H-mode plasma using combined auxiliary heating by co-neutral beam injection (NBI) and electron cyclotron resonance heating (ECH). The ion temperature and toroidal rotation are measured with x-ray imaging crystal spectroscopy and charge exchange recombination spectroscopy. H-mode plasma is achieved using co-current 1.3MW NBI, and a 0.35MW ECH pulse is added to the flat-top of H-mode. The core rotation profiles, which are centrally peaked in the pure NBI heating phase, flatten when ECH is injected, while the edge pedestal is unchanged. Dramatic decreases in the core toroidal rotation values (Delta V-tor/V-tor similar to -30%) are observed when on-axis ECH is added to H-mode. The experimental data show that the decrease of core rotation velocity and its gradient are correlated with the increase of core electron temperature and its gradient, and also with the likely steepening of the density gradient. We thus explore the viability of a hypothesized ITG (ITG ion temperature gradient instability) -> TEM (trapped electron mode instability) transition as the explanation of the observed counter-current flow induced by ECH. However, the results of linear microstability analyses using inferred profiles suggest that the TEM is excited only in the deep core, so the viability of the hypothesized explanation is not yet clear. (10.1088/0029-5515/53/11/113031)
    DOI : 10.1088/0029-5515/53/11/113031
  • Dynamics of tilted eddies in a transversal flow at the edge of tokamak plasmas and the consequences for L-H transition
    • Fedorczak N.
    • Ghendrih Philippe
    • Hennequin Pascale
    • Tynan G.R.
    • Diamond P.H.
    • Manz P.
    Plasma Physics and Controlled Fusion, IOP Publishing, 2013, 55 (12), pp.124024. The dynamical interaction between eddies and shear flow is investigated through a simplified model of vorticity conservation with tilted eddies. Energy is transferred either to the flow or to eddies, depending on the eddy tilt with respect to the flow shear. When eddies are tilted in the shear direction, the system is favorable to shear increase: tilt instability (TI) or the negative viscosity phenomenon. When eddies are tilted in the opposite direction, the shear flow is damped via a Kelvin-Helmholtz (KH) process. The TI generally dominates the interaction on the largest radial scale, but a fraction of the energy cascades to smaller radial scales through the alternation of tilting and KH dynamics. Within this eddy description, we show that the symmetry breaking required to generate a net residual stress is set by the intrinsic eddy tilt. We recall that magnetic shear can provide an intrinsic tilt to ballooning modes at the edge of tokamak plasmas, with an orientation which depends on flux surface geometry. In L-mode weak shear regimes, this residual stress can dominate the Reynolds stress. Coupled to momentum sources acting in the scrape-off layer, it can induce a significant difference of the edge radial electric field between lower single null and upper single null geometries. A comparison with experimental profiles measured across the edge of Tore Supra L-mode plasmas is discussed. (10.1088/0741-3335/55/12/124024)
    DOI : 10.1088/0741-3335/55/12/124024
  • Theory of a Strip Loop Antenna Located on the Surface of an Axially Magnetized Plasma Column
    • Kudrin A. V.
    • Zaitseva Anna S
    • Zaboronkova T. M.
    • Krafft C.
    • Kyriacou George A
    Progress In Electromagnetics Research B, EMW Publishing, 2013, 51, pp.221--246. We study the current distribution and input impedance of a circular loop antenna in the form of an infinitesimally thin, perfectly conducting narrow strip coiled into a ring. The antenna is located on the surface of an axially magnetized plasma column surrounded by a homogeneous isotropic medium. The current in the antenna is excited by a time-harmonic voltage creating an electric field with the azimuthal component in a gap of small angular opening on the strip surface. The emphasis is placed on the solution of the integral equations for the azimuthal harmonics of the antenna current in the case where the magnetoplasma inside the column is nonresonant. The properties of the kernels of the integral equations are discussed and the current distribution in the antenna is obtained. It is shown that the presence of a magnetized plasma column can significantly influence the electrodynamic characteristics of the antenna compared with the case where it is located in the surrounding medium or a homogeneous plasma medium the parameters of which coincide with those inside the column. (10.2528/PIERB13032304)
    DOI : 10.2528/PIERB13032304
  • Plasma/surface interaction: example of air plasmas and plasma bullets
    • Guaitella Olivier
    , 2013.
  • Cavitation in the vicinity of the high-voltage electrode as a key step of nanosecond breakdown in liquids
    • Marinov Ilya
    • Guaitella Olivier
    • Rousseau Antoine
    • Starikovskaia Svetlana
    Plasma Sources Science and Technology, IOP Publishing, 2013, 22, pp.042001. Fast shadowgraphy of nanosecond discharge in liquids with different dielectric permittivity, namely in water, ethanol and n-pentane, has been performed. Formation of a gas cavity at a nanosecond time scale was observed as a pre-breakdown phenomenon at amplitudes of the high-voltage pulse close to the breakdown threshold. This phenomenon is considered as a possible key step of high-voltage breakdown in polar liquids. (10.1088/0963-0252/22/4/042001)
    DOI : 10.1088/0963-0252/22/4/042001
  • Radio-frequency capacitively coupled plasmas excited by tailored voltage waveforms: comparison of experiment and particle-in-cell simulations
    • Delattre Pierre-Alexandre
    • Lafleur Trevor
    • Johnson Erik
    • Booth Jean-Paul
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.235201. Using a range of different diagnostics we have performed a detailed experimental characterization of a capacitively coupled rf plasma discharge excited by tailored voltage waveforms in argon (3?13 Pa). The applied pulse-type tailored waveforms consist of between 1 and 5 harmonics (with a fundamental of 15 MHz), and are used to generate an electrically asymmetric plasma response, manifested by the formation of a strong dc bias in the geometrically symmetric reactor used. Experimental measurements of the dc bias, electron density, ion current density, ion-flux energy distributions at the electrodes and discharge current waveforms, are compared with a one-dimensional particle-in-cell simulation for the same operating conditions. The experimental and simulation results are found to be in good agreement over the range of parameters investigated, and demonstrate a number of unique features present with pulse-type tailored waveforms, including: increased plasma density and ion flux with the number of harmonics, and a broader control range of the ion bombarding energy. (10.1088/0022-3727/46/23/235201)
    DOI : 10.1088/0022-3727/46/23/235201
  • Negative ion extraction from hydrogen plasma bulk
    • Oudini N.
    • Taccogna F.
    • Minelli P.
    • Aanesland Ane
    • Raimbault Jean-Luc
    Physics of Plasmas, American Institute of Physics, 2013, 20 (10), pp.103506. A two-dimensional particle-in-cell/Monte Carlo collision model has been developed and used to study low electronegative magnetized hydrogen plasma. A configuration characterized by four electrodes is used: the left electrode is biased at Vl&#8201;=&#8201;&#8722;100&#8201;V, the right electrode is grounded, while the upper and lower transversal electrodes are biased at an intermediate voltage Vud between 0 and &#8722;100&#8201;V. A constant and homogeneous magnetic field is applied parallel to the lateral (left/right) electrodes. It is shown that in the magnetized case, the bulk plasma potential is close to the transversal electrodes bias inducing then a reversed sheath in front of the right electrode. The potential drop within the reversed sheath is controlled by the transversal electrodes bias allowing extraction of negative ions with a significant reduction of co-extracted electron current. Furthermore, introducing plasma electrodes, between the transversal electrodes and the right electrode, biased with a voltage just above the plasma bulk potential, increases the negative ion extracted current and decreases significantly the co-extracted electron current. The physical mechanism on basis of this phenomenon has been discussed. (10.1063/1.4825246)
    DOI : 10.1063/1.4825246
  • Direct observation of ozone formation on SiO<SUB>2</SUB> surfaces in O<SUB>2</SUB> discharges
    • Marinov Daniil
    • Guaitella Olivier
    • Booth Jean-Paul
    • Rousseau Antoine
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.032001. Ozone production is studied in a pulsed O2 discharge at pressures in the range 1.36.7 mbar. Time-resolved absolute concentrations of O3 and O are measured in the post-discharge using UV absorption spectroscopy and two-photon absorption laser-induced fluorescence. In a bare silica discharge tube ozone is formed mainly by three-body gas-phase recombination. When the tube surface is covered by a high specific surface silica catalyst heterogeneous formation becomes the main source of ozone. The efficiency of this surface process increases with O2 pressure and is favoured by the presence of OH groups and adsorbed H2O on the surface. At p = 6.7 mbar ozone production accounts for up to 25% of the atomic oxygen losses on the surface. (10.1088/0022-3727/46/3/032001)
    DOI : 10.1088/0022-3727/46/3/032001
  • Space Research in Africa. Some Achievements from 2007 to 2012
    • Amory-Mazaudier Christine
    • Fleury Rolland
    Sun and Geosphere, BBC SWS Regional Network, 2013, 2 (8), pp.65-70. This article presents the results of a research network Europe Africa established in 1995 after the International Electrojet Equatorial Year (1992-1994). During the last decade, this research network has been involved in two international projects: the International Heliophysical Year (2007-2009) and International Space Weather Initiative (2010-2012).The participation in these international projects increased the number of PhD and multiplied the number of scientific papers. Many scientific results have been obtained. Teaching and working methods have been also developed. We emphasize in this article the last two points.
  • A study of helium atmospheric-pressure guided streamers for potential biological applications
    • Gazeli Kristacq
    • Noel Cédric
    • Clement Franck
    • Dauge C.
    • Svarnas P.
    • Belmonte Thierry
    Plasma Sources Science and Technology, IOP Publishing, 2013, 22 (2), pp.025020. The origin of differences in the rotational temperatures of various molecules and ions (N-2(+)(B), OH(A) and N-2(C)) is studied in helium atmospheric-pressure guided streamers. The rotational temperature of N-2(+)(B) is room temperature. It is estimated from the emission band of the first negative system at 391.4 nm, and it is governed by the temperature of N-2(X) in the surrounding air. N-2(X) is ionized by direct electron impact in the outer part of the plasma. N-2(+)(B) is deactivated by collisions with N-2 and O-2. The rotational temperature of OH(A), estimated from the OH band at 306.4 nm, is slightly higher than that of N-2(+)(B). OH(A) is excited by electron impact with H2O during the first 100 ns of the applied voltage pulse. Next, OH(A) is produced by electron impact with OH(X) created by the quenching of OH(A) by N-2 and O-2. H2O diffuses deeper than N-2 into the plasma ring and the rotational temperature of OH(A) is slightly higher than that of N-2(+)(B). The rotational temperature of N-2(C), estimated from the emission of the second positive system at 315.9 nm, is governed by its collisions with helium. The gas temperature of helium at the beginning of the pulse is predicted to be several hundred kelvin higher than room temperature. (10.1088/0963-0252/22/2/025020)
    DOI : 10.1088/0963-0252/22/2/025020
  • In Situ Cassini Spacecraft Observations of Turbulence in Saturn's Magnetosheath
    • Hadid L. Z.
    • Sahraoui Fouad
    • Retinò Alessandro
    • Modolo Ronan
    • Canu Patrick
    • Jackman C. M.
    • Masters A.
    • Dougherty M. K.
    • Gurnett D. A.
    , 2013, 8, pp.EPSC2013-1056. Throughout this work we investigate, the properties of turbulence in the Magnetosheath of Saturn. To do so, we computed Power Spectral Densities (PSD) based on Cassini interplanetary magnetic field data between 2004 and 2007. As a preliminary result, we show the absence of the Kolmogorov scale ~ f-5/3 in the inertial range whereas only the f-1 scale is present.
  • Fine-structure-resolved electron collisions from chlorine atoms in the (3p<SUP>5</SUP>)<SUP>2</SUP>P<SUB>3/2</SUB><SUP>o</SUP> and (3p<SUP>5</SUP>)<SUP>2</SUP>P<SUB>1/2</SUB><SUP>o</SUP> states
    • Wang Yang
    • Zatsarinny Oleg
    • Bartschat Klaus
    • Booth Jean-Paul
    Physical Review A : Atomic, molecular, and optical physics [1990-2015], American Physical Society, 2013, 87, pp.022703. The B-spline R-matrix method is employed to calculate elastic electron scattering from chlorine atoms in the (3p5)2P3/2,1/2o states and electron-induced collisions between these two finestructure levels. The polarizability of the target states is accounted for by including polarized pseudostates in the close-coupling expansion, while relativistic effects are treated at the level of the semirelativistic Breit-Pauli approximation. We find the Ramsauer minimum in the elastic channels at a significantly lower projectile energy (&#8776;0.2 eV) than previous calculations, due to an apparent strong sensitivity of the theoretical predictions on the details of the model, especially the target structure. The present results are relevant to the determination of chlorine atomic densities in Cl2-containing industrial plasma etch reactors. (10.1103/PhysRevA.87.022703)
    DOI : 10.1103/PhysRevA.87.022703
  • Electrical characteristics of micro-hollow cathode discharges
    • Lazzaroni Claudia
    • Chabert Pascal
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.455203. A cathode sheath model of micro-hollow cathode discharges is proposed to calculate the voltagecurrent characteristics and discuss the physics of the discharge resistance. Three different approaches are compared: (i) a self-consistent model where the electric field is determined self-consistently with the electron flux, (ii) a matrix sheath model where the electric field profile in the sheath is imposed, (iii) a constant electric field model where the electric field in the sheath is assumed to be equal to a constant fraction of the electric field at the cathode. The sheath size is found to decrease with the pressure, the voltage and the secondary emission coefficient. There is a strong effect of the secondary emission coefficient and the pressure on the voltagecurrent characteristics. The discharge resistance is found to be several hundreds of k&#937; and decreases with the discharge current, the pressure and the secondary emission coefficient. A comparison between the matrix sheath model and experiments suggests that both the secondary emission coefficient and the surface area on which the current is collected at the cathode increase with the discharge current. This increase is related to a transition between a discharge confined in the hole at low current and a plasma abruptly expanded on the cathode backside at higher current. (10.1088/0022-3727/46/45/455203)
    DOI : 10.1088/0022-3727/46/45/455203
  • On the reactivity of plasma-treated photo-catalytic TiO<SUB>2</SUB> surfaces for oxidation of C<SUB>2</SUB>H<SUB>2</SUB> and CO
    • Lopatik D.
    • Marinov Daniil
    • Guaitella Olivier
    • Rousseau Antoine
    • Roepcke J.
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.255203. The objective of this study is to understand fundamental aspects of interactions of plasmas with catalytic surfaces. Based on this approach the reactivity of plasma treated and stimulated catalytic surfaces of TiO2 is studied by analysing the oxidation (i) of C2H2 to CO and CO2 and (ii) of CO to CO2. The inner surface of a Pyrex discharge tube is coated with TiO2 films impregnated with TiO2 nanoparticles, which provides a surface area of about 4 m2. In addition to the exposure of the TiO2 surface by low-pressure radio-frequency plasmas using O2, Ar or N2 (f = 13.56 MHz, p = 0.53 mbar, P = 17 W) the surfaces are stimulated by heating and UV radiation treatment. The temporal development of the concentrations of the precursor gases C2H2 or CO and of the reaction products is monitored using quantum cascade laser absorption spectroscopy, which provides multi-component detection in the mid-infrared spectral range. The C2H2 concentration was found to be nearly constant over time after a pre-treatment with Ar or N2 discharges using an initial gas mixture of 1% C2H2 in Ar. However, a strong decay of the concentration of C2H2 is observed for pure O2 plasma pre-treatment. In general, the decay is found to be nearly exponential with time constant in the order of about 10 min. The reactive adsorption of C2H2 molecules on the inner surface of the tube reactor showed a density of about 7.5 × 1012 C2H2 molecules cm&#8722;2. This behaviour demonstrates that the reaction (\rm O_\rm ads \rm C_2 \rm H_2)_\rm TiO_2 produces some adsorbed intermediates, which can be thermally or photo-catalytically oxidized to CO2. In contrast, when 1% CO in Ar is used as an initial gas mixture no adsorption processes on the TiO2 surface could be detected. An effective destruction of CO took part via photo-catalytic oxidation. (10.1088/0022-3727/46/25/255203)
    DOI : 10.1088/0022-3727/46/25/255203
  • Controlled deposition of sulphur-containing semiconductor and dielectric nano-structured films on metals in SF<SUB>6</SUB> ion-ion plasma
    • Rafalskyi D.V.
    • Bredin Jérôme
    • Aanesland Ane
    Journal of Applied Physics, American Institute of Physics, 2013, 114 (21), pp.213303. In the present paper, the deposition processes and formation of films in SF6 ion-ion plasma, with positive and negative ion flows accelerated to the surface, are investigated. The PEGASES (acronym for Plasma Propulsion with Electronegative GASES) source is used as an ion-ion plasma source capable of generating almost ideal ion-ion plasma with negative ion to electron density ratio more than 2500. It is shown that film deposition in SF6 ion-ion plasma is very sensitive to the polarity of the incoming ions. The effect is observed for Cu, W, and Pt materials. The films formed on Cu electrodes during negative and positive ion assisted deposition were analyzed. Scanning electron microscope analysis has shown that both positive and negative ion fluxes influence the copper surface and leads to film formation, but with different structures of the surface: the low-energy positive ion bombardment causes the formation of a nano-pored film transparent for ions, while the negative ion bombardment leads to a continuous smooth insulating film. The transversal size of the pores in the porous film varies in the range 50500&#8201;nm, and further analysis of the film has shown that the film forms a diode together with the substrate preventing positive charge drain, and positive ions are neutralized by passing through the nano-pores. The film obtained with the negative ion bombardment has an insulating surface, but probably with a multi-layer structure: destroying the top surface layer allows to measure similar diode IV-characteristics as for the nano-pored film case. Basing on results, practical conclusions for the probes and electrodes cleaning in ion-ion SF6 plasmas have been made. Different applications are proposed for the discovered features of the controlled deposition from ion-ion plasmas, from Li-sulphur rechargeable batteries manufacturing and nanofluidics issues to the applications for microelectronics, including low-k materials formation. (10.1063/1.4842915)
    DOI : 10.1063/1.4842915
  • Hysteresis effects in the formation of a neutralizing beam plasma at low ion energy
    • Rafalskyi D.V.
    • Aanesland Ane
    EPL - Europhysics Letters, European Physical Society / EDP Sciences / Società Italiana di Fisica / IOP Publishing, 2013, 104 (3), pp.35004. In this paper, the PEGASES II thruster prototype is used as an ion source generating low-energy positive Ar ion beam, extracted without an external neutralizer. The ions are extracted and accelerated from the source using a two-grid system. The extracted positive ion beam current is measured on a large beam target that can be translated along the acceleration axis. The ion beam current shows a stepwise transition from a low-current to a high-current extraction regime with hysteresis. The hysteresis region depends strongly upon the beam target position. Langmuir probe measurements in the plume show high plasma potentials and low plasma densities in the low-current mode, while the plasma potential drops and the density increases in the high-current mode. The ion energy distribution functions of the beam are measured for different regimes of ion extraction. The ion beam extracted in the high-current mode is indicated by the presence of an additional low-energy peak corresponding to ions from an ion-beam plasma created in the downstream chamber, as well as 1020 times higher intensity of the primary ion beam peak. The hysteresis behavior is explained by the formation of a downstream neutralizing beam plasma, that depends on the target position and pressure in agreement with a Paschen-like breakdown by secondary electrons. The obtained results are of high relevance for further development of the PEGASES thruster, as well as for improving existing neutralizer-free concepts of the broad-beam ion sources. (10.1209/0295-5075/104/35004)
    DOI : 10.1209/0295-5075/104/35004