Publications

2014

Mars-Solar Wind Interaction: Coupling Between Hybrid, Ionospheric, Thermospheric and Exospheric Models
- Leblanc François
- Chaufray Jean-Yves
- Modolo Ronan
- Hess Sebastien
- Yagi M.
- Mancini M.
- Forget François
- Gonzalez-Galindo Francisco
- Lorenzato L.
- Mazelle Christian
- Chanteur Gérard
, 2014. The solar wind interaction with the Martian neutral envi- ronment is investigated by means of three dimensional hybrid magnetospheric simulations. In such formal- ism, ions have a kinetic description while electrons are treated as an inertialess fluid, ensuring the neutrality of the plasma and contributing to currents and pressure terms. This model has been successfully used to de- scribe the near ionized environment of Mars
Ignition of CH4:O2:Ar and n-C4H10:O2:Ar(N2) mixtures with initial temperatures between 650-950 K by a surface pulsed discharge
- Stepanyan S.A.
- Boumehdi M.A.
- Vanhove G.
- Desgroux Pascale
- Starikovskaia Svetlana
- Popov N.A.
, 2014. (10.2514/6.2014-0665)
DOI : 10.2514/6.2014-0665
Experimental and numerical study of fast gas heating and O atom production in a capillary nanosecond discharge
- Klochko A.V.
- Salmon A.
- Lemainque J.
- Popov N.A.
- Booth Jean-Paul
- Xiong Z.
- Kushner M.J.
- Starikovskaia Svetlana
, 2014, pp.2014-1030.
Adsorption, desorption and reactivity of O and N atoms on SiO2 surface
- Rousseau Antoine
, 2014.
New ferromagnetic core shapes for induction sensors
- Coillot Christophe
- Moutoussamy Joël
- Boda Mathieu
- Leroy Paul
Journal of Sensors and Sensor Systems, Copernicus Publ, 2014, pp.1-8. Induction sensors are used in a wide range of scientific and industrial applications. One way to improve these is rigorous modelling of the sensor combined with a low voltage and current input noise preamplifier aiming to optimize the whole induction magnetometer. In this paper, we explore another way, which consists in the use of original ferromagnetic core shapes of induction sensors, which bring substantial improvements. These new configurations are the cubic, orthogonal and coiled-core induction sensors. For each of them we give modelling elements and discuss their benefits and drawbacks with respect to a given noise-equivalent magnetic induction goal. Our discussion is supported by experimental results for the cubic and orthogonal configurations, while the coiled-core configuration remains open to experimental validation. The transposition of these induction sensor configurations to other magnetic sensors (fluxgate and giant magneto-impedance) is an exciting prospect of this work. (10.5194/jsss-3-1-2014)
DOI : 10.5194/jsss-3-1-2014
NO oxidation on plasma pretreated Pyrex: the case for a distribution of reactivity of adsorbed O atoms
- Guerra V.
- Marinov Daniil
- Guaitella Olivier
- Rousseau Antoine
Journal of Physics D: Applied Physics, IOP Publishing, 2014, 47 (22), pp.224012. The formation of NO 2 molecules on a Pyrex surface, as a result of NO oxidation by adsorbed O atoms on the wall, is experimentally demonstrated and quantified. The measurements reveal that the characteristic times of heterogeneous NO 2 production and NO gas phase decay change from ?60 to ?1500 s as the gas phase concentration of NO introduced in a tube pretreated with an oxygen radiofrequency discharge increases from 10 13 to 10 15 cm ?3 . Moreover, a clear variation of the characteristic loss frequency of NO molecules when small amounts of NO are successively injected in the tube is detected, between ?7 × 10 ?2 and ?5 × 10 ?3 s ?1 . The complex surface kinetics observed is studied and interpreted with the help of a mesoscopic surface model accounting for Eley?Rideal NO oxidation and slow NO 2 adsorption, confirming the existence of adsorption sites possessing a distribution of reactivity on the surface. (10.1088/0022-3727/47/22/224012)
DOI : 10.1088/0022-3727/47/22/224012
Kinetic simulations of electric field structure within magnetic island during magnetic reconnection and their applications to the satellite observations
- Huang S. Y.
- Zhou M.
- Yuan Z. G.
- Deng X. H.
- Sahraoui Fouad
- Pang Y.
- Fu S. Y.
Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119, pp.7402-7412. islands are considered to play a crucial role in collisionless magnetic reconnection. We use particle-in-cell simulations to investigate electric field Ez structure in the magnetic islands (including primary and secondary islands) with and without a guide field during magnetic reconnection. It is found that the electric field has multilayers in the primary island and a large bipolar structure in the secondary island in the absence of guide field. The electric field is provided by the Hall term (J × B)z (mainly), the divergence of electron pressure tensor, and the convective term (Vi × B)z in the outer and the inner region of primary island, while the electric field is much smaller (~0) in the middle and the core region of primary island due to the cancelation of the three terms. The single bipolar electric field is primarily provided by the Hall term in the secondary island. In the presence of a guide field, the electric field has multiple layers in the primary island (similar to zero guide field case) and the secondary island. However, there still exists one single large sharp bipolar structure of electric field in the central region of the secondary island. The differences of electric field in the primary and secondary islands are essentially due to the variations of the current Jy. These features can be used as the observational criteria to identify different types of magnetic islands in the magnetosphere using the data of future mission, such as the Magnetospheric Multiscale mission. (10.1002/2014JA020054)
DOI : 10.1002/2014JA020054
Compact hohlraum configuration with parallel planar-wire-array x-ray sources at the 1.7-MA Zebra generator
- Vesey R. A.
- Kantsyrev Viktor L.
- Chuvatin Alexandre S.
- Rudakov Leonid I.
- Velikovich A. L.
- Shreshta I. K.
- Esaulov A. A.
- Safronova Alla S.
- Shlyaptseva V. V.
- Osborne Glenn C.
- Astanovitsky A. L.
- Weller Michael E.
- Stafford A.
- Schultz K. A.
- Cooper M. C.
- Cuneo Michael E.
- Jones B.
Physical Review E, American Physical Society (APS), 2014, 90 (6), pp.063101. A compact Z-pinch x-ray hohlraum design with parallel-driven x-ray sources is experimentally demonstrated in a configuration with a central target and tailored shine shields at a 1.7-MA Zebra generator. Driving in parallel two magnetically decoupled compact double-planar-wire Z pinches has demonstrated the generation of synchronized x-ray bursts that correlated well in time with x-ray emission from a central reemission target. Good agreement between simulated and measured hohlraum radiation temperature of the central target is shown. The advantages of compact hohlraum design applications for multi-MA facilities are discussed. (10.1103/PhysRevE.90.063101)
DOI : 10.1103/PhysRevE.90.063101
BV technique for investigating 1-D interfaces
- Dorville Nicolas
- Belmont Gérard
- Rezeau Laurence
- Aunai Nicolas
- Retinò Alessandro
Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119, pp.1709-1720. To investigate the internal structure of the magnetopause with spacecraft data, it is crucial to be able to determine its normal direction and to convert the measured time series into spatial profiles. We propose here a new single-spacecraft method, called the BV method, to reach these two objectives. Its name indicates that the method uses a combination of the magnetic field (B) and velocity (V) data. The method is tested on simulation and on Cluster data, and a short overview of the possible products is given. We discuss its assumptions and show that it can bring a valuable improvement with respect to previous methods. (10.1002/2013JA018926)
DOI : 10.1002/2013JA018926
Electron transport parameters in NF3
- Lisovskiy V. A.
- Yegorenkov V. D.
- Ogloblina P.
- Booth Jean-Paul
- Martins S.
- Landry K.
- Douai D.
- Cassagne V.
Journal of Physics D: Applied Physics, IOP Publishing, 2014, 47 (11), pp.115203. We present electron transport parameters (the first Townsend coefficient, the dissociative attachment coefficient, the fraction of electron energy lost by collisions with NF 3 molecules, the average and characteristic electron energy, the electron mobility and the drift velocity) in NF 3 gas calculated from published elastic and inelastic electron?NF 3 collision cross-sections using the BOLSIG code. Calculations were performed for the combined RB (Rescigno 1995 Phys. Rev. E 52 [http://dx.doi.org/10.1103/PhysRevA.52.329] 329 , Boesten et al 1996 J. Phys. B: At. Mol. Opt. Phys. 29 [http://dx.doi.org/10.1088/0953-4075/29/22/022] 5475 ) momentum-transfer cross-section, as well as for the JB (Joucoski and Bettega 2002 J. Phys. B: At. Mol. Opt. Phys. 35 [http://dx.doi.org/10.1088/0953-4075/35/4/303] 783 ) momentum-transfer cross-section. In addition, we have measured the radio frequency (rf) breakdown curves for various inter-electrode gaps and rfs, and from these we have determined the electron drift velocity in NF 3 from the location of the turning point in these curves. These drift velocity values are in satisfactory agreement with those calculated by the BOLSIG code employing the JB momentum-transfer cross-section. (10.1088/0022-3727/47/11/115203)
DOI : 10.1088/0022-3727/47/11/115203
Radio-frequency capacitively coupled plasmas in hydrogen excited by tailored voltage waveforms: comparison of simulations with experiments
- Diomede P.
- Economou D. J.
- Lafleur Trevor
- Booth Jean-Paul
- Longo S.
Plasma Sources Science and Technology, IOP Publishing, 2014, 23 (6), pp.065049. A combined computational-experimental study was performed of a geometrically symmetric capacitively coupled plasma in hydrogen sustained by tailored voltage waveforms consisting of the sum of up to three harmonics. Predictions of a particle-in-cell with Monte Carlo collisions/fluid hybrid model were in reasonably good agreement compared to data from an array of experimental plasma diagnostics. The plasma was electrically asymmetric, with a dc self-bias developed, for all but a sinusoidal voltage waveform. Hydrogen ions (H ,H 2,H 3) bombarding the electrodes exhibited different ion flux-distribution functions due to their different masses and collisionality in the sheath. Plasma density, ion flux and absolute value of the dc self-bias all increased with increasing the number of harmonics. The energy of ions bombarding the substrate electrode may be controlled by switching the applied voltage waveform from (positive) peaks to (negative) valleys. (10.1088/0963-0252/23/6/065049)
DOI : 10.1088/0963-0252/23/6/065049
Langmuir probe analysis in electronegative plasmas
- Bredin Jérôme
- Chabert Pascal
- Aanesland Ane
Physics of Plasmas, American Institute of Physics, 2014, 21 (12), pp.123502. This paper compares two methods to analyze Langmuir probe data obtained in electronegative plasmas. The techniques are developed to allow investigations in plasmas, where the electronegativity α0 = n/ne (the ratio between the negative ion and electron densities) varies strongly. The first technique uses an analytical model to express the Langmuir probe current-voltage (I-V) characteristic and its second derivative as a function of the electron and ion densities (ne, n , n), temperatures (Te, T , T), and masses (me, m , m). The analytical curves are fitted to the experimental data by adjusting these variables and parameters. To reduce the number of fitted parameters, the ion masses are assumed constant within the source volume, and quasi-neutrality is assumed everywhere. In this theory, Maxwellian distributions are assumed for all charged species. We show that this data analysis can predict the various plasma parameters within 510%, including the ion temperatures when α0 > 100. However, the method is tedious, time consuming, and requires a precise measurement of the energy distribution function. A second technique is therefore developed for easier access to the electron and ion densities, but does not give access to the ion temperatures. Here, only the measured I-V characteristic is needed. The electron density, temperature, and ion saturation current for positive ions are determined by classical probe techniques. The electronegativity α0 and the ion densities are deduced via an iterative method since these variables are coupled via the modified Bohm velocity. For both techniques, a Child-Law sheath model for cylindrical probes has been developed and is presented to emphasize the importance of this model for small cylindrical Langmuir probes. (10.1063/1.4903328)
DOI : 10.1063/1.4903328
Evidence of magnetic reconnection from wave measurements at Saturn's magnetopause: Cassini RPWS observations
- Retinò Alessandro
- Masters A.
- Vaivads A.
- Khotyaintsev Y. V.
- Fujimoto M.
- Kasahara S.
- Badman S. V.
- Canu Patrick
- Chust Thomas
- Modolo Ronan
- Gurnett D. A.
- Dougherty M. K.
, 2014, 9, pp.EPSC2014-802. Magnetic reconnection is a universal mechanism that is responsible for major energy conversion in planetary magnetospheres. Recent theoretical estimations suggest that reconnection is infrequent at Saturn's magnetopause and that it is not a major driver of the dynamics of the kronian magnetosphere. This scenario need however to be confirmed by in situ observations at the magnetopause current sheet. Evidence of reconnection in the form of accelerated plasma jets is difficult at Saturn's magnetopause due to limitations in the field of view of particle detectors. Here we show evidence of reconnection for one magnetopause event by using measurements of low frequency waves (lower-hybrid, whistlers, plasma/upper hybrid). We discuss how wave measurements can be used as evidence of reconnection in planetary magnetospheres.
Outflow and plasma acceleration in Titan's induced magnetotail: Evidence of magnetic tension forces
- Romanelli N.
- Modolo Ronan
- Dubinin E.
- Berthelier Jean-Jacques
- Bertucci C.
- Wahlund J. E.
- Leblanc François
- Canu Patrick
- Edberg Niklas Jt
- Waite H.
- Kurth W. S.
- Gurnett D.
- Coates A.
- Dougherty M.
Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119 (12), pp.9992–10005. Cassini plasma wave and particle observations are combined with magnetometer measurements to study Titan's induced magnetic tail. In this study, we report and analyze the plasma acceleration in Titan's induced magnetotail observed in flybys T17, T19 and T40. Radio and Plasma Wave Science (RPWS) observations show regions of cold plasma with electron densities between 0.1 and a few tens of electrons per cubic centimeter. The Cassini Plasma Spectrometer-Ion Mass Spectrometer (CAPS-IMS) measurements suggest that ionospheric plasma in this region is composed of ions with masses ranging from 15 to 17 amu and from 28 to 31 amu. From these measurements, we determine the bulk velocity of the plasma and the Alfvén velocity in Titan's tail region. Finally, a Walén test of such measurements suggest that the progressive acceleration of the ionospheric plasma shown by CAPS can be interpreted in terms of magnetic tension forces. (10.1002/2014JA020391)
DOI : 10.1002/2014JA020391
Magnetic clouds' structure in the magnetosheath as observed by Cluster and Geotail: four case studies
- Turc Lucile
- Fontaine Dominique
- Savoini Philippe
- Kilpua E. K. J.
Annales Geophysicae, European Geosciences Union, 2014, 32, pp.1247-1261. Magnetic clouds (MCs) are large-scale magnetic flux ropes ejected from the Sun into the interplanetary space. They play a central role in solar-terrestrial relations as they can efficiently drive magnetic activity in the near-Earth environment. Their impact on the Earth's magnetosphere is often attributed to the presence of southward magnetic fields inside the MC, as observed in the upstream solar wind. However, when they arrive in the vicinity of the Earth, MCs first encounter the bow shock, which is expected to modify their properties, including their magnetic field strength and direction. If these changes are significant, they can in turn affect the interaction of the MC with the magnetosphere. In this paper, we use data from the Cluster and Geotail spacecraft inside the magnetosheath and from the Advanced Composition Explorer (ACE) upstream of the Earth's environment to investigate the impact of the bow shock's crossing on the magnetic structure of MCs. Through four example MCs, we show that the evolution of the MC's structure from the solar wind to the magnetosheath differs largely from one event to another. The smooth rotation of the MC can either be preserved inside the magnetosheath, be modified, i.e. the magnetic field still rotates slowly but at different angles, or even disappear. The alteration of the magnetic field orientation across the bow shock can vary with time during the MC's passage and with the location inside the magnetosheath. We examine the conditions encountered at the bow shock from direct observations, when Cluster or Geotail cross it, or indirectly by applying a magnetosheath model. We obtain a good agreement between the observed and modelled magnetic field direction and shock configuration, which varies from quasi-perpendicular to quasi-parallel in our study. We find that the variations in the angle between the magnetic fields in the solar wind and in the magnetosheath are anti-correlated with the variations in the shock obliquity. When the shock is in a quasi-parallel regime, the magnetic field direction varies significantly from the solar wind to the magnetosheath. In such cases, the magnetic field reaching the magnetopause cannot be approximated by the upstream magnetic field. Therefore, it is important to take into account the conditions at the bow shock when estimating the impact of an MC with the Earth's environment because these conditions are crucial in determining the magnetosheath magnetic field, which then interacts with the magnetosphere. (10.5194/angeo-32-1247-2014)
DOI : 10.5194/angeo-32-1247-2014
A model of the magnetosheath magnetic field during magnetic clouds
- Turc Lucile
- Fontaine Dominique
- Savoini Philippe
- Kilpua E.K.J.
Annales Geophysicae, European Geosciences Union, 2014, 32 (2), pp.157-173. Magnetic clouds (MCs) are huge interplanetary structures which originate from the Sun and have a paramount importance in driving magnetospheric storms. Before reaching the magnetosphere, MCs interact with the Earth's bow shock. This may alter their structure and therefore modify their expected geoeffectivity. We develop a simple 3-D model of the magnetosheath adapted to MCs conditions. This model is the first to describe the interaction of MCs with the bow shock and their propagation inside the magnetosheath. We find that when the MC encounters the Earth centrally and with its axis perpendicular to the Sun–Earth line, the MC's magnetic structure remains mostly unchanged from the solar wind to the magnetosheath. In this case, the entire dayside magnetosheath is located downstream of a quasi-perpendicular bow shock. When the MC is encountered far from its centre, or when its axis has a large tilt towards the ecliptic plane, the MC's structure downstream of the bow shock differs significantly from that upstream. Moreover, the MC's structure also differs from one region of the magnetosheath to another and these differences vary with time and space as the MC passes by. In these cases, the bow shock configuration is mainly quasi-parallel. Strong magnetic field asymmetries arise in the mag-netosheath; the sign of the magnetic field north–south component may change from the solar wind to some parts of the magnetosheath. We stress the importance of the B x component. We estimate the regions where the magnetosheath and magnetospheric magnetic fields are anti-parallel at the mag-netopause (i.e. favourable to reconnection). We find that the location of anti-parallel fields varies with time as the MCs move past Earth's environment, and that they may be situated near the subsolar region even for an initially northward magnetic field upstream of the bow shock. Our results point out the major role played by the bow shock configuration in modifying or keeping the structure of the MCs unchanged. Note that this model is not restricted to MCs, it can be used to describe the magnetosheath magnetic field under an arbitrary slowly varying interplanetary magnetic field. (10.5194/angeo-32-157-2014)
DOI : 10.5194/angeo-32-157-2014
Momentum transport in the vicinity of qmin in reverse shear tokamaks due to ion temperature gradient turbulence
- Singh Rameswar
- Singh R.
- Jhang Hogun
- Diamond P.H.
Physics of Plasmas, American Institute of Physics, 2014, 21 (1), pp.012302. This paper presents effects of finite ballooning angles on linear ion temperature gradient (ITG) driven mode and associated heat and momentum flux in Gyrokinetic flux tube simulation GENE. It is found that zero ballooning angle is not always the one at which the linear growth rate is maximum. The ITG mode acquires a short wavelength (SW) branch (k⊥ρi > 1) when growth rates maximized over all ballooning angles are considered. However, the SW branch disappears on reducing temperature gradient showing characteristics of zero ballooning angle SWITG in case of extremely high temperature gradient. Associated heat flux is even with respect to ballooning angle and maximizes at nonzero ballooning angle while the parallel momentum flux is odd with respect to the ballooning angle. (10.1063/1.4861625)
DOI : 10.1063/1.4861625
Experimental characterization of plasma formation and shockwave propagation induced by high power pulsed underwater electrical discharge
- Claverie Alain
- Deroy Julien
- Boustié Michel
- Avrillaud Gilles
- Chuvatin Alexandre S.
- Mazanchenko Ekaterina
- Demol G.
- Dramane B.
Review of Scientific Instruments, American Institute of Physics, 2014, 85 (06), pp.063701. High power pulsed electrical discharges into liquids are investigated for new industrial applications based on the efficiency of controlled shock waves. We present here new experimental data obtained by combination of detailed high speed imaging equipments. It allows the visualization of the very first instants of plasma discharge formation, and then the pulsations of the gaseous bubble with an accurate timing of events. The time history of the expansion/compression of this bubble leads to an estimation of the energy effectively transferred to water during the discharge. Finally, the consecutive shock generation driven by this pulsating bubble is optically monitored by shadowgraphs and schlieren setup. These data provide essential information about the geometrical pattern and chronometry associated with the shock wave generation and propagation. (10.1063/1.4879715)
DOI : 10.1063/1.4879715
Finite ballooning angle effects on ion temperature gradient driven mode in gyrokinetic flux tube simulations
- Singh Rameswar
- Brunner Stephan
- Ganesh R.
- Jenko F.
Physics of Plasmas, American Institute of Physics, 2014, 21 (3), pp.032115. This paper presents effects of finite ballooning angles on linear ion temperature gradient (ITG) driven mode and associated heat and momentum flux in Gyrokinetic flux tube simulation GENE. It is found that zero ballooning angle is not always the one at which the linear growth rate is maximum. The ITG mode acquires a short wavelength (SW) branch (k⊥ρi > 1) when growth rates maximized over all ballooning angles are considered. However, the SW branch disappears on reducing temperature gradient showing characteristics of zero ballooning angle SWITG in case of extremely high temperature gradient. Associated heat flux is even with respect to ballooning angle and maximizes at nonzero ballooning angle while the parallel momentum flux is odd with respect to the ballooning angle. (10.1063/1.4868425)
DOI : 10.1063/1.4868425
Quantified energy dissipation rates in the terrestrial bow shock: 2. Waves and dissipation
- Wilson Iii L. B.
- Sibeck David G.
- Breneman A. W.
- Le Contel Olivier
- Cully C. M.
- Turner D. L.
- Angelopoulos V.
- Malaspina D. M.
Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119 (8), pp.6475-6495. We present the first quantified measure of the energy dissipation rates, due to wave-particle interactions, in the transition region of the Earth's collisionless bow shock using data from the Time History of Events and Macroscale Interactions during Substorms spacecraft. Our results show that wave-particle interactions can regulate the global structure and dominate the energy dissipation of collisionless shocks. In every bow shock crossing examined, we observed both low-frequency (<10 Hz) and high-frequency (≳10 Hz) electromagnetic waves throughout the entire transition region and into the magnetosheath. The low-frequency waves were consistent with magnetosonic-whistler waves. The high-frequency waves were combinations of ion-acoustic waves, electron cyclotron drift instability driven waves, electrostatic solitary waves, and whistler mode waves. The high-frequency waves had the following: (1) peak amplitudes exceeding deltaB 10 nT and deltaE 300 mV/m, though more typical values were deltaB 0.1-1.0 nT and deltaE 10-50 mV/m; (2) Poynting fluxes in excess of 2000 muW m-2 (typical values were 1-10 muW m-2); (3) resistivities > 9000 Omega m; and (4) associated energy dissipation rates >10 muW m-3. The dissipation rates due to wave-particle interactions exceeded rates necessary to explain the increase in entropy across the shock ramps for 90% of the wave burst durations. For 22% of these times, the wave-particle interactions needed to only be <= 0.1% efficient to balance the nonlinear wave steepening that produced the shock waves. These results show that wave-particle interactions have the capacity to regulate the global structure and dominate the energy dissipation of collisionless shocks. (10.1002/2014JA019930)
DOI : 10.1002/2014JA019930
A nanosecond surface dieletric barrier discharge in air at high pressure and different polarities of applied pulses. Transition to filamentary mode
- Stepanyan S.A.
- Starikovskiy a Yu
- Popov N.A.
- Starikovskaia Svetlana
Plasma Sources Science and Technology, IOP Publishing, 2014, 23 (4), pp.045003. The development of a nanosecond surface dielectric barrier discharge in air at pressures 16 bar is studied. At atmospheric pressure, the discharge develops as a set of streamers starting synchronously from the high-voltage electrode and propagating along the dielectric layer. Streamers cover the dielectric surface creating a 'quasi-uniform' plasma layer. At high pressures and high voltage amplitudes on the cathode, filamentation of the discharge is observed a few nanoseconds after the discharge starts. Parameters of the observed 'streamers-to-filaments' transition are measured; physics of transition is discussed on the basis of theoretical estimates and numerical modeling. Ionization-heating instability on the boundary of the cathode layer is suggested as a mechanism of filamentation. (10.1088/0963-0252/23/4/045003)
DOI : 10.1088/0963-0252/23/4/045003
Oxidation of isopropanol and acetone adsorbed on TiO2 under plasma generated ozone flow: Gas phase and adsorbed species monitoring
- Barakat Christelle
- Gravejat Paul
- Guaitella Olivier
- Thévenet Frédéric
- Rousseau Antoine
Applied Catalysis B: Environmental, Elsevier, 2014, 147, pp.302-313. The regeneration of isopropanol (IPA) and/or acetone saturated TiO2 surface by ozone is investigated. TiO2 catalyst is placed downstream a dielectric barrier discharge and is subsequently exposed to ozone considered as the main oxidative species generated by non-thermal plasma and able to interact with the material surface at room temperature. The oxidation of isopropanol and/or acetone is monitored using two parallel and complementary infrared diagnostics: (1) Fourier Transform Infrared Spectroscopy for the analysis of the gas phase composition; and (2) Diffuse Reflectance Infrared Fourier Transform Spectroscopy for the in situ analysis of the adsorbent/catalyst surface. In this study, the pollutant is first adsorbed on the TiO2 surface, the plasma being switched off. The irreversibly adsorbed amounts of isopropanol and acetone have been respectively quantified as 5.3 μmol/m2 and 1.9 μmol/m2. In a second step, the plasma is switched on to regenerate the surface by mineralization of the adsorbed organic species. A 70-min plasma phase, with approximately 20 ppm of ozone constantly flowing through the adsorbent bed yields 8.5 nmol and 8.9 nmol of CO2 per injected joule of energy for isopropanol and acetone saturated surfaces, respectively. Acetone has been evidenced as the main oxidation intermediate of isopropanol on TiO2 surface. It has been proven that the complete oxidation of isopropanol and acetone is mainly limited by the acetone oxidation rate. Competitive adsorption on the surface of the catalyst between both compounds has been studied. Results obtained are compared with those observed in the photocatalytic oxidation of the same species. (10.1016/j.apcatb.2013.09.008)
DOI : 10.1016/j.apcatb.2013.09.008
Ambipolar and non-ambipolar diffusion in an rf plasma source containing a magnetic filter
- Lafleur Trevor
- Aanesland Ane
Physics of Plasmas, American Institute of Physics, 2014, 21, pp.063510. By placing a magnetic filter across a rectangular plasma source (closed at one end with a ceramic plate and an rf antenna, and terminated at the opposite end by a grounded grid), we experimentally investigate the effect of conducting and insulating source walls on the nature of the plasma diffusion phenomena. The use of a magnetic filter creates a unique plasma, characterized by a high upstream electron temperature (Teu∼5 eV) near the rf antenna and a low downstream electron temperature (Ted∼1 eV) near the grid, which more clearly demonstrates the role of the source wall materials. For conducting walls a net ion current to ground is measured on the grid, and the plasma potential is determined by a mean electron temperature within the source. For insulating walls the plasma potential is determined by the downstream electron temperature (i.e., Vp∼5.2Ted in argon), and the net current to the grid is exactly zero. Furthermore, by inserting a small additional upstream conductor (that can be made floating or grounded through an external circuit switch), we demonstrate that the plasma potential can be controlled and set to a low (Vp∼5.2Ted), or high (Vp∼5.2Teu) value. (10.1063/1.4885109)
DOI : 10.1063/1.4885109
Surface deactivation of vibrationally excited N2 studied using infrared titration combined with quantum cascade laser absorption spectroscopy
- Marinov Daniil
- Lopatik D.
- Guaitella Olivier
- Ionikh Y.
- Röpcke J.
- Rousseau Antoine
Journal of Physics D: Applied Physics, IOP Publishing, 2014, 47 (1), pp.015203. The wall de-excitation probability of vibrationally excited nitrogen molecules was determined using infrared (IR) titration with CO, CO 2 and N 2 O. Gas mixtures of N 2 with 0.05?0.5% of CO (CO 2 or N 2 O) were excited by a pulsed dc discharge at p = 133 Pa in a cylindrical discharge tube. During the afterglow, the vibrational relaxation of titrating molecules was monitored in situ with quantum cascade laser absorption spectroscopy. The value of was deduced from measured vibrational relaxation times using a model of vibrational kinetics in N 2 . It was found that adsorption of IR tracers on the surface may increase the value of by a factor up to two, depending on the molecule and the surface material. It was demonstrated that N 2 O is the most inert and reliable tracer and it was used for the determination of on silica, Pyrex, TiO 2 , Al 2 O 3 and anodized aluminum. Pretreatment of the silica surface by low-pressure plasma was found to have a strong effect on the vibrational de-excitation. Values of measured after O 2 , Ar and N 2 plasma pretreatment of the same silica discharge tube were 5.7 × 10 ?4 , 8.2 × 10 ?4 and 11 × 10 ?4 , respectively. This study clearly demonstrates that the presence of adsorbed atoms and molecules on the surface may significantly alter the value of . (10.1088/0022-3727/47/1/015203)
DOI : 10.1088/0022-3727/47/1/015203
Pulsed discharges in a wide density range: plasma development and media excitation
- Starikovskaia Svetlana
- Starikovskii A.Yu.
, 2014. The Chapter demonstrates the peculiarities of pulsed nonequilibrium plasma generation in different media by nano- and picosecond high-voltage discharges. Fast ionization waves in long tubes at low pressures, streamers and dielectric barrier discharges at moderate and atmospheric pressures, surface dielectric barrier discharges at elevated pressures are considered. Special attention is given to start of picoseconds and nanosecond discharges in liquid media. The data used were consciously restricted to ICCD fast imaging of picoseconds and nanosecond discharges, to underline the dynamics of pulsed discharge development and the importance of spatial distribution of the discharge energy.

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