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Publications

Sont listées ci-dessous, par année, les publications figurant dans l'archive ouverte HAL.

2013

  • Nonlinear saturation of wave packets excited by low-energy electron horseshoe distributions
    • Krafft C.
    • Volokitin A.
    Physical Review E, American Physical Society (APS), 2013, 87, pp.053107. Horseshoe distributions are shell-like particle distributions that can arise in space and laboratory plasmas when particle beams propagate into increasing magnetic fields. The present paper studies the stability and the dynamics of wave packets interacting resonantly with electrons presenting low-energy horseshoe or shell-type velocity distributions in a magnetized plasma. The linear instability growth rates are determined as a function of the ratio of the plasma to the cyclotron frequencies, of the velocity and the opening angle of the horseshoe, and of the relative thickness of the shell. The nonlinear stage of the instability is investigated numerically using a symplectic code based on a three-dimensional Hamiltonian model. Simulation results show that the dynamics of the system is mainly governed by wave-particle interactions at Landau and normal cyclotron resonances and that the high-order normal cyclotron resonances play an essential role. Specific features of the dynamics of particles interacting simultaneously with two or more waves at resonances of different natures and orders are discussed, showing that such complex processes determine the main characteristics of the wave spectrum's evolution. Simulations with wave packets presenting quasicontinuous spectra provide a full picture of the relaxation of the horseshoe distribution, revealing two main phases of the evolution: an initial stage of wave energy growth, characterized by a fast filling of the shell, and a second phase of slow damping of the wave energy, accompanied by final adjustments of the electron distribution. The influence of the density inhomogeneity along the horseshoe on the wave-particle dynamics is also discussed. (10.1103/PhysRevE.87.053107)
    DOI : 10.1103/PhysRevE.87.053107
  • Physics of Stimulated L->H Transitions
    • Miki K.
    • Diamond P.H.
    • Hahn S. -H.
    • Xiao W. W.
    • Gürcan Özgür D.
    • Tynan G.R.
    Physical Review Letters, American Physical Society, 2013, 110, pp.195002. We report on model studies of stimulated L&#8594;H transitions. These studies use a novel reduced mesoscale model. Studies reveal that L&#8594;H transitions can be triggered by particle injection into a subcritical state (i.e., P<PThresh). Particle injection alters the edge mean flow shear via changes of density and temperature gradients. The change of edge mean flow shear is critical to turbulence collapse and the subsequent stimulated transition. For low ambient heating, strong injection is predicted to trigger a transient turbulence collapse. We predict that repetitive injection can maintain the turbulence collapse and so sustain a driven H-mode-like state. The total number of particles required to induce a transition by either injection or gas puffing is estimated. Results indicate that the total number of injected particles required is much smaller than that required for inducing a transition by gas puffing. Thus, we show that internal injection is more efficient than gas puffing of comparable strength. We also observe that zonal flows do not play a critical role in stimulated transitions. (10.1103/PhysRevLett.110.195002)
    DOI : 10.1103/PhysRevLett.110.195002
  • CLUSTER observation of polar electron precipitation above the polar caps during periods of Northward IMF
    • Fontaine Dominique
    • Maggiolo R.
    AGU Fall Meeting Abstracts, AGU, 2013, 21, pp.07. The CLUSTER spacecraft revealed the presence of successive current sheets of opposite polarity above the polar caps during periods of northward or weak IMF. We first present the general electrodynamical context. At CLUSTER altitude (5-7 RE), the upward part of this current system consists of ion beams accelerated by quasi-static electric fields, associated with precipitating electrons. They are surrounded by low energy upflowing electron beams carrying a downward current. We then focus on the precipitating electrons above the polar cap which form acceleration structures at about 100 - 300 eV. This acceleration is interpreted as the effect of an electrostatic potential along magnetic field lines located above CLUSTER altitude, i.e. typically above 5-7 RE. We present statistics on the characteristics of these precipitating electron structures and we discuss the source regions and the mechanisms possibly at their origin.
  • Anisotropy of radiation emitted from planar wire arrays
    • Kantsyrev Viktor L.
    • Chuvatin Alexandre S.
    • Esaulov A. A.
    • Safronova Alla S.
    • Rudakov Leonid I.
    • Velikovich A. L.
    • Williamson Kenneth M.
    • Osborne Glenn C.
    • Shrestha I. K.
    • Weller Michael E.
    • Shlyaptseva V. V.
    Physics of Plasmas, American Institute of Physics, 2013, 20 (07), pp.070702. The planar wire array (PWA) is a promising load for new multi-source inertial confinement fusion (ICF) hohlraums [B. Jones et al. Phys. Rev. Lett. 104 125001 (2010)]. The hohlraum radiation symmetry is an important issue for ICF. It was found that extreme ultraviolet and sub-keV photon emission from PWAs may have considerable anisotropy in the load azimuthal plane. This experimental result is obtained on the UNR 11.7 MA Zebra generator. The time-dependent anisotropy effect is detected. This feature is studied in 2D numerical simulations and can be explained by initial anisotropy of implosion of those non-cylindrical loads radiating essentially as surface sources in sub-keV quanta and also by radiation absorption in cold magnetized plasma tails forming in the direction of magnetic compression. (10.1063/1.4817023)
    DOI : 10.1063/1.4817023
  • A spectroscopic study of ethylene destruction and by-product generation using a three-stage atmospheric packed-bed plasma reactor
    • Hubner Antoine
    • Guaitella Olivier
    • Rousseau Antoine
    • Roepcke J.
    Journal of Applied Physics, American Institute of Physics, 2013, 114, pp.033301. Using a three-stage dielectric packed-bed plasma reactor at atmospheric pressure, the destruction of ethylene, a typical volatile organic compound, and the generation of major by-products have been studied by means of Fourier Transform Infrared Spectroscopy. A test gas mixture air at a gas flow of 1 slm containing 0.12% humidity with 0.1% ethylene has been used. In addition to the fragmentation of the precursor gas, the evolution of the concentration of ten stable reaction products, CO, CO2, O3, NO2, N2O, HCN, H2O, HNO3, CH2O, and CH2O2 has been monitored. The concentrations of the by-products range between 5&#8201;ppm, in the case of NO2, and 1200&#8201;ppm, for H2O. By the application of three sequentially working discharge cells at a frequency of f&#8201;=&#8201;4 kHz and voltage values between 9 and 12&#8201;kV, a nearly complete decomposition of C2H4 could be achieved. Furthermore, the influence of the specific energy deposition (SED) on the destruction process has been studied and the maximum value of SED was about 900 J l&#8722;1. The value of the characteristic energy &#946;, characterizing the energy efficiency of the ethylene destruction in the reactor, was found to be 330 J l&#8722;1. It was proven that the application of three reactor stages suppresses essentially the production of harmful by-products as formaldehyde, formic acid, and NO2 compared to the use of only one or two stages. Based on the multi-component detection, the carbon balance of the plasma chemical conversion of ethylene has been analyzed. The dependence of the fragmentation efficiencies of ethylene (RF(C2H4)&#8201;=&#8201;5.5&#8201;×&#8201;1019 molecules J&#8722;1) and conversion efficiencies to the produced molecular species (RC&#8201;=&#8201;(0.13)&#8201;×&#8201;1016 molecules J&#8722;1) on the discharge conditions could be estimated in the multistage plasma reactor. (10.1063/1.4813409)
    DOI : 10.1063/1.4813409
  • Isopropanol saturated TiO<SUB>2</SUB> surface regeneration by non-thermal plasma : Influence of air relative humidity
    • Sivachandiran Loganathan
    • Thévenet Frédéric
    • Gravejat Paul
    • Rousseau Antoine
    Chemical Engineering Journal, Elsevier, 2013, 214, pp.17-26. Environmental regulation on air quality requires the development of energetic efficient volatile organic compounds (VOCs) abatement techniques. Adsorption, photocatalysis, non-thermal plasma and their combinations have been widely studied for VOC treatment. Even if the plasma material (sorbent or catalyst) association appears as one of the most efficient configuration for VOC removal, it mainly consists in operating continuously the discharge on the material surface as long as the effluent flows across the reactor. This work aims at investigating another approach of plasma material association for VOC removal: in a first step, the material is used as a sorbent until the complete coverage of adsorption sites; in a second step, once VOC saturation is achieved, the discharge is ignited on the material surface. During both steps, the influence of air relative humidity (RH) is investigated in order to evaluate its impact on the process. The objectives of our approach are: (i) the reduction of energy consumption; (ii) the increase of sorbent life-times by efficient regeneration; (iii) the investigation of plasma interaction with VOC saturated materials; (iv) the investigation of air RH influence on such VOC treatment process. A packed bed reactor coated with TiO2 has been designed. IPA is used as a model VOC. First, injected power in the packed-bed reactor is characterized as a function of air RH. Complete coverage of TiO2 surface over 35% RH is suggested as a significant parameter. Then, adsorption of IPA on TiO2 was monitored until IPA breakthrough. The amount of IPA adsorbed per TiO2 surface unit is compared to values reported by other authors. The influence of air RH on reversibly and irreversibly adsorbed IPA fractions is investigated. Over 35% RH irreversible adsorption is favored, adsorption modes are discussed. Plasma regeneration of IPA saturated TiO2 surface leads simultaneously to IPA desorption and mineralization. Increasing air RH favors IPA mineralization and diminishes acetone production. Carbon balance obtained after 1 h plasma treatment reaches 91% in the presence of 50% RH. A thermal treatment is performed after each plasma treatment in order to evidence plasma insensitive adsorbed species and to restore TiO2 initial surface state. 97% of the carbon balance is collected under 50% RH after thermal treatment. During the thermal step, acetone and CO2 are mainly produced, their formation pathways are discussed. (10.1016/j.cej.2012.10.022)
    DOI : 10.1016/j.cej.2012.10.022
  • Influence of the dissipation mechanism on collisionless magnetic reconnection in symmetric and asymmetric current layers
    • Aunai Nicolas
    • Hesse Michael
    • Black Carrie
    • Evans Rebekah
    • Kuznetsova M. M.
    Physics of Plasmas, American Institute of Physics, 2013, 20, pp.2901. Numerical studies implementing different versions of the collisionless Ohm's law have shown a reconnection rate insensitive to the nature of the non-ideal mechanism occurring at the X line, as soon as the Hall effect is operating. Consequently, the dissipation mechanism occurring in the vicinity of the reconnection site in collisionless systems is usually thought not to have a dynamical role beyond the violation of the frozen-in condition. The interpretation of recent studies has, however, led to the opposite conclusion that the electron scale dissipative processes play an important dynamical role in preventing an elongation of the electron layer from throttling the reconnection rate. This work re-visits this topic with a new approach. Instead of focusing on the extensively studied symmetric configuration, we aim to investigate whether the macroscopic properties of collisionless reconnection are affected by the dissipation physics in asymmetric configurations, for which the effect of the Hall physics is substantially modified. Because it includes all the physical scales a priori important for collisionless reconnection (Hall and ion kinetic physics) and also because it allows one to change the nature of the non-ideal electron scale physics, we use a (two dimensional) hybrid model. The effects of numerical, resistive, and hyper-resistive dissipation are studied. In a first part, we perform simulations of symmetric reconnection with different non-ideal electron physics. We show that the model captures the already known properties of collisionless reconnection. In a second part, we focus on an asymmetric configuration where the magnetic field strength and the density are both asymmetric. Our results show that contrary to symmetric reconnection, the asymmetric model evolution strongly depends on the nature of the mechanism which breaks the field line connectivity. The dissipation occurring at the X line plays an important role in preventing the electron current layer from elongating and forming plasmoids. (10.1063/1.4795727)
    DOI : 10.1063/1.4795727
  • Remote sensing of a NTC radio source from a Cluster tilted spacecraft pair
    • Décréau Pierrette
    • Kougblénou S.
    • Lointier G.
    • Rauch Jean-Louis
    • Trotignon Jean-Gabriel
    • Vallières X.
    • Canu Patrick
    • Rochel Grimald S.
    • El-Lemdani Mazouz Farida
    • Darrouzet F.
    Annales Geophysicae, European Geosciences Union, 2013, 31 (11), pp.2097-2121. The Cluster mission operated a "tilt campaign" during the month of May 2008. Two of the four identical Cluster spacecraft were placed at a close distance (~50 km) from each other and the spin axis of one of the spacecraft pair was tilted by an angle of ~46°. This gave the opportunity, for the first time in space, to measure global characteristics of AC electric field, at the sensitivity available with long boom (88 m) antennas, simultaneously from the specific configuration of the tilted pair of satellites and from the available base of three satellites placed at a large characteristic separation (~1 RE). This paper describes how global characteristics of radio waves, in this case the configuration of the electric field polarization ellipse in 3-D-space, are identified from in situ measurements of spin modulation features by the tilted pair, validating a novel experimental concept. In the event selected for analysis, non-thermal continuum (NTC) waves in the 15-25 kHz frequency range are observed from the Cluster constellation placed above the polar cap. The observed intensity variations with spin angle are those of plane waves, with an electric field polarization close to circular, at an ellipticity ratio e = 0.87. We derive the source position in 3-D by two different methods. The first one uses ray path orientation (measured by the tilted pair) combined with spectral signature of magnetic field magnitude at source. The second one is obtained via triangulation from the three spacecraft baseline, using estimation of directivity angles under assumption of circular polarization. The two results are not compatible, placing sources widely apart. We present a general study of the level of systematic errors due to the assumption of circular polarization, linked to the second approach, and show how this approach can lead to poor triangulation and wrong source positioning. The estimation derived from the first method places the NTC source region in the dawn sector, at a large L value (L ~ 10) and a medium geomagnetic latitude (35° S). We discuss these untypical results within the frame of the geophysical conditions prevailing that day, i.e. a particularly quiet long time interval, followed by a short increase of magnetic activity. (10.5194/angeo-31-2097-2013)
    DOI : 10.5194/angeo-31-2097-2013
  • On the supply of heavy planetary material to the magnetotail of Mercury
    • Delcourt Dominique C.
    Annales Geophysicae, European Geosciences Union, 2013, 31 (10), pp.1673-1679. We examine the transport of low-energy heavy ions of planetary origin (O + , Na + , Ca +) in the magneto-sphere of Mercury. We show that, in contrast to Earth, these ions are abruptly energized after ejection into the magneto-sphere due to enhanced curvature-related parallel acceleration. Regardless of their mass-to-charge ratio, the parallel speed of these ions is rapidly raised up to ∼ 2 V E×B (denoting by V E×B the magnitude of the local E × B drift speed), in a like manner to Fermi-type acceleration by a moving magnetic mirror. This parallel energization is such that ions with very low initial energies (a few tenths of eVs) can overcome gravity and, regardless of species or convection rate, are transported over comparable distances into the night-side magnetosphere. The region of space where these ions reach the magnetotail is found to extend over altitudes similar to those where enhanced densities are noticeable in the MESSENGER data, viz., from ∼ 1000 km up to ∼ 6000 km in the pre-midnight sector. The observed density enhancements may thus follow from E × B related focusing of planetary material of dayside origin into the magnetotail. Due to the planetary magnetic field offset, an asymmetry is found between drift paths anchored in the Northern and Southern hemispheres, which puts forward a predominant role of heavy material originating in the Northern Hemisphere in populating the innermost region of Mercury's magnetotail. (10.5194/angeo-31-1673-2013)
    DOI : 10.5194/angeo-31-1673-2013
  • ECH effects on toroidal rotation: KSTAR experiments, intrinsic torque modelling and gyrokinetic stability analyses
    • Shi Y. J.
    • Ko W. H.
    • Kwon J.M.
    • Diamond P.H.
    • Lee S. G.
    • Ko S. H.
    • Wang L.
    • Yi Sukyoung
    • Ida K.
    • Terzolo L.
    • Yoon S. W.
    • Lee K. D.
    • Lee J. H.
    • Nam U. N.
    • Bae Y. S.
    • Oh Y. K.
    • Kwak J. G.
    • Bitter M.
    • Hill K.
    • Gürcan Özgür D.
    • Hahm T.S.
    Nuclear Fusion, IOP Publishing, 2013, 53 (11). Toroidal rotation profiles have been investigated in KSTAR H-mode plasma using combined auxiliary heating by co-neutral beam injection (NBI) and electron cyclotron resonance heating (ECH). The ion temperature and toroidal rotation are measured with x-ray imaging crystal spectroscopy and charge exchange recombination spectroscopy. H-mode plasma is achieved using co-current 1.3MW NBI, and a 0.35MW ECH pulse is added to the flat-top of H-mode. The core rotation profiles, which are centrally peaked in the pure NBI heating phase, flatten when ECH is injected, while the edge pedestal is unchanged. Dramatic decreases in the core toroidal rotation values (Delta V-tor/V-tor similar to -30%) are observed when on-axis ECH is added to H-mode. The experimental data show that the decrease of core rotation velocity and its gradient are correlated with the increase of core electron temperature and its gradient, and also with the likely steepening of the density gradient. We thus explore the viability of a hypothesized ITG (ITG ion temperature gradient instability) -> TEM (trapped electron mode instability) transition as the explanation of the observed counter-current flow induced by ECH. However, the results of linear microstability analyses using inferred profiles suggest that the TEM is excited only in the deep core, so the viability of the hypothesized explanation is not yet clear. (10.1088/0029-5515/53/11/113031)
    DOI : 10.1088/0029-5515/53/11/113031
  • Dynamics of tilted eddies in a transversal flow at the edge of tokamak plasmas and the consequences for L-H transition
    • Fedorczak N.
    • Ghendrih Philippe
    • Hennequin Pascale
    • Tynan G.R.
    • Diamond P.H.
    • Manz P.
    Plasma Physics and Controlled Fusion, IOP Publishing, 2013, 55 (12), pp.124024. The dynamical interaction between eddies and shear flow is investigated through a simplified model of vorticity conservation with tilted eddies. Energy is transferred either to the flow or to eddies, depending on the eddy tilt with respect to the flow shear. When eddies are tilted in the shear direction, the system is favorable to shear increase: tilt instability (TI) or the negative viscosity phenomenon. When eddies are tilted in the opposite direction, the shear flow is damped via a Kelvin-Helmholtz (KH) process. The TI generally dominates the interaction on the largest radial scale, but a fraction of the energy cascades to smaller radial scales through the alternation of tilting and KH dynamics. Within this eddy description, we show that the symmetry breaking required to generate a net residual stress is set by the intrinsic eddy tilt. We recall that magnetic shear can provide an intrinsic tilt to ballooning modes at the edge of tokamak plasmas, with an orientation which depends on flux surface geometry. In L-mode weak shear regimes, this residual stress can dominate the Reynolds stress. Coupled to momentum sources acting in the scrape-off layer, it can induce a significant difference of the edge radial electric field between lower single null and upper single null geometries. A comparison with experimental profiles measured across the edge of Tore Supra L-mode plasmas is discussed. (10.1088/0741-3335/55/12/124024)
    DOI : 10.1088/0741-3335/55/12/124024
  • Space Research in Africa. Some Achievements from 2007 to 2012
    • Amory-Mazaudier Christine
    • Fleury Rolland
    Sun and Geosphere, BBC SWS Regional Network, 2013, 2 (8), pp.65-70. This article presents the results of a research network Europe Africa established in 1995 after the International Electrojet Equatorial Year (1992-1994). During the last decade, this research network has been involved in two international projects: the International Heliophysical Year (2007-2009) and International Space Weather Initiative (2010-2012).The participation in these international projects increased the number of PhD and multiplied the number of scientific papers. Many scientific results have been obtained. Teaching and working methods have been also developed. We emphasize in this article the last two points.
  • Theory of a Strip Loop Antenna Located on the Surface of an Axially Magnetized Plasma Column
    • Kudrin A. V.
    • Zaitseva Anna S
    • Zaboronkova T. M.
    • Krafft C.
    • Kyriacou George A
    Progress In Electromagnetics Research B, EMW Publishing, 2013, 51, pp.221--246. We study the current distribution and input impedance of a circular loop antenna in the form of an infinitesimally thin, perfectly conducting narrow strip coiled into a ring. The antenna is located on the surface of an axially magnetized plasma column surrounded by a homogeneous isotropic medium. The current in the antenna is excited by a time-harmonic voltage creating an electric field with the azimuthal component in a gap of small angular opening on the strip surface. The emphasis is placed on the solution of the integral equations for the azimuthal harmonics of the antenna current in the case where the magnetoplasma inside the column is nonresonant. The properties of the kernels of the integral equations are discussed and the current distribution in the antenna is obtained. It is shown that the presence of a magnetized plasma column can significantly influence the electrodynamic characteristics of the antenna compared with the case where it is located in the surrounding medium or a homogeneous plasma medium the parameters of which coincide with those inside the column. (10.2528/PIERB13032304)
    DOI : 10.2528/PIERB13032304
  • Plasma/surface interaction: example of air plasmas and plasma bullets
    • Guaitella Olivier
    , 2013.
  • Cavitation in the vicinity of the high-voltage electrode as a key step of nanosecond breakdown in liquids
    • Marinov Ilya
    • Guaitella Olivier
    • Rousseau Antoine
    • Starikovskaia Svetlana
    Plasma Sources Science and Technology, IOP Publishing, 2013, 22, pp.042001. Fast shadowgraphy of nanosecond discharge in liquids with different dielectric permittivity, namely in water, ethanol and n-pentane, has been performed. Formation of a gas cavity at a nanosecond time scale was observed as a pre-breakdown phenomenon at amplitudes of the high-voltage pulse close to the breakdown threshold. This phenomenon is considered as a possible key step of high-voltage breakdown in polar liquids. (10.1088/0963-0252/22/4/042001)
    DOI : 10.1088/0963-0252/22/4/042001
  • Radio-frequency capacitively coupled plasmas excited by tailored voltage waveforms: comparison of experiment and particle-in-cell simulations
    • Delattre Pierre-Alexandre
    • Lafleur Trevor
    • Johnson Erik
    • Booth Jean-Paul
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.235201. Using a range of different diagnostics we have performed a detailed experimental characterization of a capacitively coupled rf plasma discharge excited by tailored voltage waveforms in argon (3?13 Pa). The applied pulse-type tailored waveforms consist of between 1 and 5 harmonics (with a fundamental of 15 MHz), and are used to generate an electrically asymmetric plasma response, manifested by the formation of a strong dc bias in the geometrically symmetric reactor used. Experimental measurements of the dc bias, electron density, ion current density, ion-flux energy distributions at the electrodes and discharge current waveforms, are compared with a one-dimensional particle-in-cell simulation for the same operating conditions. The experimental and simulation results are found to be in good agreement over the range of parameters investigated, and demonstrate a number of unique features present with pulse-type tailored waveforms, including: increased plasma density and ion flux with the number of harmonics, and a broader control range of the ion bombarding energy. (10.1088/0022-3727/46/23/235201)
    DOI : 10.1088/0022-3727/46/23/235201
  • Negative ion extraction from hydrogen plasma bulk
    • Oudini N.
    • Taccogna F.
    • Minelli P.
    • Aanesland Ane
    • Raimbault Jean-Luc
    Physics of Plasmas, American Institute of Physics, 2013, 20 (10), pp.103506. A two-dimensional particle-in-cell/Monte Carlo collision model has been developed and used to study low electronegative magnetized hydrogen plasma. A configuration characterized by four electrodes is used: the left electrode is biased at Vl&#8201;=&#8201;&#8722;100&#8201;V, the right electrode is grounded, while the upper and lower transversal electrodes are biased at an intermediate voltage Vud between 0 and &#8722;100&#8201;V. A constant and homogeneous magnetic field is applied parallel to the lateral (left/right) electrodes. It is shown that in the magnetized case, the bulk plasma potential is close to the transversal electrodes bias inducing then a reversed sheath in front of the right electrode. The potential drop within the reversed sheath is controlled by the transversal electrodes bias allowing extraction of negative ions with a significant reduction of co-extracted electron current. Furthermore, introducing plasma electrodes, between the transversal electrodes and the right electrode, biased with a voltage just above the plasma bulk potential, increases the negative ion extracted current and decreases significantly the co-extracted electron current. The physical mechanism on basis of this phenomenon has been discussed. (10.1063/1.4825246)
    DOI : 10.1063/1.4825246
  • Direct observation of ozone formation on SiO<SUB>2</SUB> surfaces in O<SUB>2</SUB> discharges
    • Marinov Daniil
    • Guaitella Olivier
    • Booth Jean-Paul
    • Rousseau Antoine
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.032001. Ozone production is studied in a pulsed O2 discharge at pressures in the range 1.36.7 mbar. Time-resolved absolute concentrations of O3 and O are measured in the post-discharge using UV absorption spectroscopy and two-photon absorption laser-induced fluorescence. In a bare silica discharge tube ozone is formed mainly by three-body gas-phase recombination. When the tube surface is covered by a high specific surface silica catalyst heterogeneous formation becomes the main source of ozone. The efficiency of this surface process increases with O2 pressure and is favoured by the presence of OH groups and adsorbed H2O on the surface. At p = 6.7 mbar ozone production accounts for up to 25% of the atomic oxygen losses on the surface. (10.1088/0022-3727/46/3/032001)
    DOI : 10.1088/0022-3727/46/3/032001
  • A study of helium atmospheric-pressure guided streamers for potential biological applications
    • Gazeli Kristacq
    • Noel Cédric
    • Clement Franck
    • Dauge C.
    • Svarnas P.
    • Belmonte Thierry
    Plasma Sources Science and Technology, IOP Publishing, 2013, 22 (2), pp.025020. The origin of differences in the rotational temperatures of various molecules and ions (N-2(+)(B), OH(A) and N-2(C)) is studied in helium atmospheric-pressure guided streamers. The rotational temperature of N-2(+)(B) is room temperature. It is estimated from the emission band of the first negative system at 391.4 nm, and it is governed by the temperature of N-2(X) in the surrounding air. N-2(X) is ionized by direct electron impact in the outer part of the plasma. N-2(+)(B) is deactivated by collisions with N-2 and O-2. The rotational temperature of OH(A), estimated from the OH band at 306.4 nm, is slightly higher than that of N-2(+)(B). OH(A) is excited by electron impact with H2O during the first 100 ns of the applied voltage pulse. Next, OH(A) is produced by electron impact with OH(X) created by the quenching of OH(A) by N-2 and O-2. H2O diffuses deeper than N-2 into the plasma ring and the rotational temperature of OH(A) is slightly higher than that of N-2(+)(B). The rotational temperature of N-2(C), estimated from the emission of the second positive system at 315.9 nm, is governed by its collisions with helium. The gas temperature of helium at the beginning of the pulse is predicted to be several hundred kelvin higher than room temperature. (10.1088/0963-0252/22/2/025020)
    DOI : 10.1088/0963-0252/22/2/025020
  • Solar wind fluctuations and solar wind activity long-term swing 1963-2012
    • Zerbo J.-L.
    • Amory-Mazaudier Christine
    • Ouattara Frédéric Martial
    , 2013, 1301161.
  • In Situ Cassini Spacecraft Observations of Turbulence in Saturn's Magnetosheath
    • Hadid L. Z.
    • Sahraoui Fouad
    • Retinò Alessandro
    • Modolo Ronan
    • Canu Patrick
    • Jackman C. M.
    • Masters A.
    • Dougherty M. K.
    • Gurnett D. A.
    , 2013, 8, pp.EPSC2013-1056. Throughout this work we investigate, the properties of turbulence in the Magnetosheath of Saturn. To do so, we computed Power Spectral Densities (PSD) based on Cassini interplanetary magnetic field data between 2004 and 2007. As a preliminary result, we show the absence of the Kolmogorov scale ~ f-5/3 in the inertial range whereas only the f-1 scale is present.
  • Fine-structure-resolved electron collisions from chlorine atoms in the (3p<SUP>5</SUP>)<SUP>2</SUP>P<SUB>3/2</SUB><SUP>o</SUP> and (3p<SUP>5</SUP>)<SUP>2</SUP>P<SUB>1/2</SUB><SUP>o</SUP> states
    • Wang Yang
    • Zatsarinny Oleg
    • Bartschat Klaus
    • Booth Jean-Paul
    Physical Review A : Atomic, molecular, and optical physics [1990-2015], American Physical Society, 2013, 87, pp.022703. The B-spline R-matrix method is employed to calculate elastic electron scattering from chlorine atoms in the (3p5)2P3/2,1/2o states and electron-induced collisions between these two finestructure levels. The polarizability of the target states is accounted for by including polarized pseudostates in the close-coupling expansion, while relativistic effects are treated at the level of the semirelativistic Breit-Pauli approximation. We find the Ramsauer minimum in the elastic channels at a significantly lower projectile energy (&#8776;0.2 eV) than previous calculations, due to an apparent strong sensitivity of the theoretical predictions on the details of the model, especially the target structure. The present results are relevant to the determination of chlorine atomic densities in Cl2-containing industrial plasma etch reactors. (10.1103/PhysRevA.87.022703)
    DOI : 10.1103/PhysRevA.87.022703
  • Electrical characteristics of micro-hollow cathode discharges
    • Lazzaroni Claudia
    • Chabert Pascal
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.455203. A cathode sheath model of micro-hollow cathode discharges is proposed to calculate the voltagecurrent characteristics and discuss the physics of the discharge resistance. Three different approaches are compared: (i) a self-consistent model where the electric field is determined self-consistently with the electron flux, (ii) a matrix sheath model where the electric field profile in the sheath is imposed, (iii) a constant electric field model where the electric field in the sheath is assumed to be equal to a constant fraction of the electric field at the cathode. The sheath size is found to decrease with the pressure, the voltage and the secondary emission coefficient. There is a strong effect of the secondary emission coefficient and the pressure on the voltagecurrent characteristics. The discharge resistance is found to be several hundreds of k&#937; and decreases with the discharge current, the pressure and the secondary emission coefficient. A comparison between the matrix sheath model and experiments suggests that both the secondary emission coefficient and the surface area on which the current is collected at the cathode increase with the discharge current. This increase is related to a transition between a discharge confined in the hole at low current and a plasma abruptly expanded on the cathode backside at higher current. (10.1088/0022-3727/46/45/455203)
    DOI : 10.1088/0022-3727/46/45/455203
  • On the reactivity of plasma-treated photo-catalytic TiO<SUB>2</SUB> surfaces for oxidation of C<SUB>2</SUB>H<SUB>2</SUB> and CO
    • Lopatik D.
    • Marinov Daniil
    • Guaitella Olivier
    • Rousseau Antoine
    • Roepcke J.
    Journal of Physics D: Applied Physics, IOP Publishing, 2013, 46, pp.255203. The objective of this study is to understand fundamental aspects of interactions of plasmas with catalytic surfaces. Based on this approach the reactivity of plasma treated and stimulated catalytic surfaces of TiO2 is studied by analysing the oxidation (i) of C2H2 to CO and CO2 and (ii) of CO to CO2. The inner surface of a Pyrex discharge tube is coated with TiO2 films impregnated with TiO2 nanoparticles, which provides a surface area of about 4 m2. In addition to the exposure of the TiO2 surface by low-pressure radio-frequency plasmas using O2, Ar or N2 (f = 13.56 MHz, p = 0.53 mbar, P = 17 W) the surfaces are stimulated by heating and UV radiation treatment. The temporal development of the concentrations of the precursor gases C2H2 or CO and of the reaction products is monitored using quantum cascade laser absorption spectroscopy, which provides multi-component detection in the mid-infrared spectral range. The C2H2 concentration was found to be nearly constant over time after a pre-treatment with Ar or N2 discharges using an initial gas mixture of 1% C2H2 in Ar. However, a strong decay of the concentration of C2H2 is observed for pure O2 plasma pre-treatment. In general, the decay is found to be nearly exponential with time constant in the order of about 10 min. The reactive adsorption of C2H2 molecules on the inner surface of the tube reactor showed a density of about 7.5 × 1012 C2H2 molecules cm&#8722;2. This behaviour demonstrates that the reaction (\rm O_\rm ads \rm C_2 \rm H_2)_\rm TiO_2 produces some adsorbed intermediates, which can be thermally or photo-catalytically oxidized to CO2. In contrast, when 1% CO in Ar is used as an initial gas mixture no adsorption processes on the TiO2 surface could be detected. An effective destruction of CO took part via photo-catalytic oxidation. (10.1088/0022-3727/46/25/255203)
    DOI : 10.1088/0022-3727/46/25/255203
  • Controlled deposition of sulphur-containing semiconductor and dielectric nano-structured films on metals in SF<SUB>6</SUB> ion-ion plasma
    • Rafalskyi D.V.
    • Bredin Jérôme
    • Aanesland Ane
    Journal of Applied Physics, American Institute of Physics, 2013, 114 (21), pp.213303. In the present paper, the deposition processes and formation of films in SF6 ion-ion plasma, with positive and negative ion flows accelerated to the surface, are investigated. The PEGASES (acronym for Plasma Propulsion with Electronegative GASES) source is used as an ion-ion plasma source capable of generating almost ideal ion-ion plasma with negative ion to electron density ratio more than 2500. It is shown that film deposition in SF6 ion-ion plasma is very sensitive to the polarity of the incoming ions. The effect is observed for Cu, W, and Pt materials. The films formed on Cu electrodes during negative and positive ion assisted deposition were analyzed. Scanning electron microscope analysis has shown that both positive and negative ion fluxes influence the copper surface and leads to film formation, but with different structures of the surface: the low-energy positive ion bombardment causes the formation of a nano-pored film transparent for ions, while the negative ion bombardment leads to a continuous smooth insulating film. The transversal size of the pores in the porous film varies in the range 50500&#8201;nm, and further analysis of the film has shown that the film forms a diode together with the substrate preventing positive charge drain, and positive ions are neutralized by passing through the nano-pores. The film obtained with the negative ion bombardment has an insulating surface, but probably with a multi-layer structure: destroying the top surface layer allows to measure similar diode IV-characteristics as for the nano-pored film case. Basing on results, practical conclusions for the probes and electrodes cleaning in ion-ion SF6 plasmas have been made. Different applications are proposed for the discovered features of the controlled deposition from ion-ion plasmas, from Li-sulphur rechargeable batteries manufacturing and nanofluidics issues to the applications for microelectronics, including low-k materials formation. (10.1063/1.4842915)
    DOI : 10.1063/1.4842915